Thirteen women and children being held hostage by fighters in Gaza will be the first to be released – as the temporary truce in Gaza between Israel and Hamas begins at 7am local time (5am UK time) on Friday, Qatar has said.

Dr Majed al Ansari, spokesperson for Qatar’s foreign ministry, said it had received a list of the civilians to be freed around 4pm local time (2pm UK time) tomorrow – and families would be given priority.

He said it was expected Israel would release Palestinian prisoners in return as part of the deal.

“We are hoping that we don’t see any further delays,” he said.

“I think we have reached a point now where everything is in place, we are ready to go on the ground.”

Follow latest: Qatar gives more details on ceasefire

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Mum of hostages: ‘Without them, I lost my life’

The deal, agreed following talks mediated by Qatar, Egypt and the US, will include the Red Cross visiting the hostages and bringing medicines to them.

It would also mean hundreds of trucks carrying humanitarian, medical and fuel supplies would be allowed to enter Gaza, while Israel would halt all air missions over southern Gaza and maintain a daily six-hour daytime no-fly window in the north.

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Military analyst Sean Bell explains how the hostage handover might unfold

Dr al Ansari said humanitarian aid would start flowing into Gaza as soon as the truce begins, adding it was “a fraction” of what it needs.

The ceasefire had been set to take effect at 10am local time on Thursday (8am UK time) – after six weeks of fighting.

The structured agreement was reached and confirmed on Wednesday morning, but more than a day later an expected announcement of the official start time had yet to materialise.

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Gaza: ‘There is nowhere safe’

Asked about the delay by reporters at a news conference in Doha, Dr al Ansari said discussions had been “very difficult and detailed”.

“We wanted to make sure that nothing would cause harm in the process of getting the hostages out, and the perimeters of the agreement are agreed upon in the operational sense, on both sides,” he said.

He added the temporary truce includes a comprehensive ceasefire in both north and southern Gaza – and it was hoped it will lead to a permanent truce.

Hamas has agreed to free 50 Israeli women and child hostages held by fighters in Gaza, in exchange for Israel releasing 150 Palestinian women and children from Israeli jails.

Israel had said the truce could last beyond the initial four days as long as the fighters free at least 10 hostages per day.

A Palestinian source has told the Reuters news agency a second wave of releases could see as many as 100 hostages freed by the end of the month.

Both sides have said they will go back to fighting once the truce is over.

Israel has said more than 240 people were taken hostage and 1,200 killed, mostly civilians, during a rampage on southern Israel by Hamas and other militant groups, including Palestinian Islamic Jihad, on 7 October.

In retaliation, Israel has been bombarding the enclave for weeks as it bids to “wipe out” Hamas. At least 13,000 Palestinians have been killed in the strikes on Gaza, including at least 5,500 children, according to the Hamas-run government.